24 research outputs found
Information measures of hydrogenic systems, Laguerre polynomials and spherical harmonics
AbstractFisher's information and Shannon's entropy are two complementary information measures of a probability distribution. Here, the probability distributions which characterize the quantum-mechanical states of a hydrogenic system are analyzed by means of these two quantities. These distributions are described in terms of Laguerre polynomials and spherical harmonics, whose characteristics are controlled by the three integer quantum numbers of the corresponding states. We have found the explicit expression for the Fisher information, and a lower bound for the Shannon entropy with the help of an isoperimetric inequality
Configuration Complexities of Hydrogenic Atoms
The Fisher-Shannon and Cramer-Rao information measures, and the LMC-like or
shape complexity (i.e., the disequilibrium times the Shannon entropic power) of
hydrogenic stationary states are investigated in both position and momentum
spaces. First, it is shown that not only the Fisher information and the
variance (then, the Cramer-Rao measure) but also the disequilibrium associated
to the quantum-mechanical probability density can be explicitly expressed in
terms of the three quantum numbers (n, l, m) of the corresponding state.
Second, the three composite measures mentioned above are analytically,
numerically and physically discussed for both ground and excited states. It is
observed, in particular, that these configuration complexities do not depend on
the nuclear charge Z. Moreover, the Fisher-Shannon measure is shown to
quadratically depend on the principal quantum number n. Finally, sharp upper
bounds to the Fisher-Shannon measure and the shape complexity of a general
hydrogenic orbital are given in terms of the quantum numbers.Comment: 22 pages, 7 figures, accepted i
Spreading lengths of Hermite polynomials
The Renyi, Shannon and Fisher spreading lengths of the classical or
hypergeometric orthogonal polynomials, which are quantifiers of their
distribution all over the orthogonality interval, are defined and investigated.
These information-theoretic measures of the associated Rakhmanov probability
density, which are direct measures of the polynomial spreading in the sense of
having the same units as the variable, share interesting properties: invariance
under translations and reflections, linear scaling and vanishing in the limit
that the variable tends towards a given definite value. The expressions of the
Renyi and Fisher lengths for the Hermite polynomials are computed in terms of
the polynomial degree. The combinatorial multivariable Bell polynomials, which
are shown to characterize the finite power of an arbitrary polynomial, play a
relevant role for the computation of these information-theoretic lengths.
Indeed these polynomials allow us to design an error-free computing approach
for the entropic moments (weighted L^q-norms) of Hermite polynomials and
subsequently for the Renyi and Tsallis entropies, as well as for the Renyi
spreading lengths. Sharp bounds for the Shannon length of these polynomials are
also given by means of an information-theoretic-based optimization procedure.
Moreover, it is computationally proved the existence of a linear correlation
between the Shannon length (as well as the second-order Renyi length) and the
standard deviation. Finally, the application to the most popular
quantum-mechanical prototype system, the harmonic oscillator, is discussed and
some relevant asymptotical open issues related to the entropic moments
mentioned previously are posed.Comment: 16 pages, 4 figures. Journal of Computational and Applied Mathematics
(2009), doi:10.1016/j.cam.2009.09.04
Testing one-body density functionals on a solvable model
There are several physically motivated density matrix functionals in the
literature, built from the knowledge of the natural orbitals and the occupation
numbers of the one-body reduced density matrix. With the help of the equivalent
phase-space formalism, we thoroughly test some of the most popular of those
functionals on a completely solvable model.Comment: Latex, 16 pages, 4 figure
Reducing the environmental impact of surgery on a global scale: systematic review and co-prioritization with healthcare workers in 132 countries
Background
Healthcare cannot achieve net-zero carbon without addressing operating theatres. The aim of this study was to prioritize feasible interventions to reduce the environmental impact of operating theatres.
Methods
This study adopted a four-phase Delphi consensus co-prioritization methodology. In phase 1, a systematic review of published interventions and global consultation of perioperative healthcare professionals were used to longlist interventions. In phase 2, iterative thematic analysis consolidated comparable interventions into a shortlist. In phase 3, the shortlist was co-prioritized based on patient and clinician views on acceptability, feasibility, and safety. In phase 4, ranked lists of interventions were presented by their relevance to high-income countries and low–middle-income countries.
Results
In phase 1, 43 interventions were identified, which had low uptake in practice according to 3042 professionals globally. In phase 2, a shortlist of 15 intervention domains was generated. In phase 3, interventions were deemed acceptable for more than 90 per cent of patients except for reducing general anaesthesia (84 per cent) and re-sterilization of ‘single-use’ consumables (86 per cent). In phase 4, the top three shortlisted interventions for high-income countries were: introducing recycling; reducing use of anaesthetic gases; and appropriate clinical waste processing. In phase 4, the top three shortlisted interventions for low–middle-income countries were: introducing reusable surgical devices; reducing use of consumables; and reducing the use of general anaesthesia.
Conclusion
This is a step toward environmentally sustainable operating environments with actionable interventions applicable to both high– and low–middle–income countries
Parameter-based Fisher's information of orthogonal polynomials
AbstractThe Fisher information of the classical orthogonal polynomials with respect to a parameter is introduced, its interest justified and its explicit expression for the Jacobi, Laguerre, Gegenbauer and Grosjean polynomials found
Modified Clebsch-Gordan-type expansions for products of discrete hypergeometric polynomials.
Starting from the second-order difference hypergeometric equation satisfied by the set of discrete orthogonal polynomials fpn g, we find the analytical expressions of the expansion coefficients of any polynomial r m (x) and of the product r m (x)q j (x) in series of the set fpng. These coefficients are given in terms of the polynomial coefficients of the second-order difference equations satisfied by the involved discrete hypergeometric polynomials. Here q j (x) denotes an arbitrary discrete hypergeometric polynomial of degree j. The particular cases in which fr m g corresponds to the nonorthogonal families fx m g, the rising factorials or Pochhammer polynomials f(x) m g and the falling factorial or Stirling polynomials fx [m] g are considered in detail. The connection problem between discrete hypergeometric polynomials, which here corresponds to the product case with m = 0, is also studied and its complete solution for all the classical discrete orthogonal hypergeometric (CDOH) p..